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Butter the bottom and sides of four 6 oz ramekins. Sprinkle sugar inside each one and tip the sugar around to coat all sides. Dump out excess sugar.
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Melt the butter and chocolate chips in a medium-sized microwave-safe bowl for about 1 minute or more until melted. Stir together until the chocolate is melted and smooth.
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Stir in the powdered sugar.
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Whisk in the eggs, egg yolk and vanilla.
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Stir in the flour and salt.
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Divide the batter evenly between the prepared ramekins.
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If you'd like, add semi sweet chocolate chips into the center of the ramekin to guarantee the chocolate flow after cooking.
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Pour 2 cups of water into the inner pot of the Instant Pot, and place the trivet into the water.
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Place 3 ramekins on the trivet and place 1 more on top of them, in the middle (staggered). Close the Instant Pot. Make sure the steam release knob is pointed to the ‘Sealing’ position.
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Pressure Cook for 13 minutes.
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Do a Quick Release of steam and open the Instant Pot.
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Use oven mitts to gently remove the ramekins from the Instant Pot. Gently dab off any condensation from the top of each cake.
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Gently run a knife around the rim of the cake inside the ramekin. Flip the ramekin upside down onto a plate and let gravity pull the cake out of the ramekin. Lift the ramekin off the plate.
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Dust the chocolate cakes with powdered sugar. Garnish with fresh raspberries.
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Serve warm with vanilla ice cream and enjoy!